No | Compound | RI* | Treatment | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
M0DS100** | M50DS100 | M100DS100 | M150DS100 | M0DS70 | M50DS70 | M100DS70 | M150DS70 | M0DS40 | M50DS40 | M100DS40 | M150DS40 | |||
1 | α-Thujene | 824 | 0.65 ± 0.02 | 0.58 ± 0.01 | 0.56 ± 0.01 | 0.57 ± 0.01 | 0.56 ± 0.03 | 0.51 ± 0.01 | 0.53 ± 0.01 | 0.56 ± 0.04 | 0.50 ± 0.01 | 0.54 ± 0.02 | 0.45 ± 0.02 | 0.54 ± 0.04 |
2 | α-Pinene | 829 | 0.49 ± 0.01 | 0.41 ± 0.02 | 0.37 ± 0.02 | 0.35 ± 0.01 | 0.43 ± 0.03 | 0.46 ± 0.04 | 0.40 ± 0.01 | 0.39 ± 0.01 | 0.34 ± 0.03 | 0.28 ± 0.01 | 0.33 ± 0.03 | 0.30 ± 0.01 |
3 | Camphene | 846 | 0.45 ± 0.02 | 0.43 ± 0.02 | 0.40 ± 0.01 | 0.37 ± 0.02 | 0.44 ± 0.01 | 0.44 ± 0.03 | 0.50 ± 0.02 | 0.34 ± 0.01 | 0.41 ± 0.04 | 0.36 ± 0.04 | 0.32 ± 0.03 | 0.31 ± 0.01 |
4 | Myrcene | 889 | 0.81 ± 0.06 | 0.65 ± 0.03 | 0.51 ± 0.06 | 0.45 ± 0.06 | 0.53 ± 0.04 | 0.47 ± 0.08 | 0.36 ± 0.02 | 0.36 ± 0.03 | 0.39 ± 0.02 | 0.34 ± 0.04 | 0.35 ± 0.02 | 0.30 ± 0.03 |
5 | 2-Ethylhexanol | 898 | 0.24 ± 0.01 | 0.19 ± 0.01 | 0.16 ± 0.01 | 0.13 ± 0.01 | 0.18 ± 0.01 | 0.15 ± 0.01 | 0.16 ± 0.01 | 0.15 ± 0.01 | 0.17 ± 0.01 | 0.12 ± 0.00 | 0.14 ± 0.01 | 0.13 ± 0.00 |
6 | α-Terpinene | 916 | 0.98 ± 0.06 | 0.91 ± 0.05 | 0.85 ± 0.02 | 0.73 ± 0.05 | 0.90 ± 0.04 | 0.87 ± 0.06 | 0.81 ± 0.03 | 0.75 ± 0.05 | 0.74 ± 0.04 | 0.70 ± 0.04 | 0.70 ± 0.05 | 0.64 ± 0.02 |
7 | p-Cymene | 925 | 15.33 ± 0.38 | 14.23 ± 0.12 | 9.18 ± 0.22 | 8.32 ± 0.45 | 13.45 ± 0.12 | 9.41 ± 0.19 | 8.08 ± 0.25 | 6.92 ± 0.29 | 10.30 ± 0.23 | 8.72 ± 0.33 | 7.35 ± 0.12 | 5.78 ± 0.14 |
8 | Limonene | 928 | 0.82 ± 0.05 | 0.46 ± 0.02 | 0.37 ± 0.04 | 0.31 ± 0.02 | 0.51 ± 0.04 | 0.42 ± 0.05 | 0.37 ± 0.03 | 0.34 ± 0.05 | 0.35 ± 0.04 | 0.32 ± 0.02 | 0.31 ± 0.03 | 0.25 ± 0.01 |
9 | γ-Terpinene | 960 | 5.15 ± 0.12 | 4.62 ± 0.14 | 4.20 ± 0.10 | 3.34 ± 0.09 | 4.94 ± 0.11 | 4.75 ± 0.08 | 3.55 ± 0.04 | 3.31 ± 0.02 | 4.72 ± 0.12 | 3.40 ± 0.05 | 2.95 ± 0.08 | 1.80 ± 0.06 |
10 | Linalool | 999 | 1.97 ± 0.09 | 1.94 ± 0.05 | 1.88 ± 0.07 | 1.91 ± 0.05 | 1.91 ± 0.03 | 1.94 ± 0.05 | 1.89 ± 0.06 | 1.92 ± 0.04 | 1.94 ± 0.03 | 1.82 ± 0.02 | 1.86 ± 0.04 | 1.85 ± 0.02 |
11 | Isoborneol | 1070 | 3.66 ± 0.09 | 3.62 ± 0.07 | 3.58 ± 0.04 | 3.61 ± 0.05 | 3.51 ± 0.04 | 3.14 ± 0.03 | 3.14 ± 0.05 | 1.91 ± 0.04 | 3.32 ± 0.08 | 2.97 ± 0.05 | 2.94 ± 0.02 | 1.81 ± 0.01 |
12 | Terpinen-4-ol | 1079 | 1.35 ± 0.02 | 1.36 ± 0.02 | 1.30 ± 0.01 | 1.31 ± 0.02 | 1.25 ± 0.02 | 1.31 ± 0.01 | 1.33 ± 0.01 | 1.31 ± 0.01 | 1.30 ± 0.02 | 1.27 ± 0.01 | 1.30 ± 0.02 | 1.26 ± 0.01 |
13 | α-Terpineol | 1109 | 0.17 ± 0.02 | 0.13 ± 0.01 | 0.16 ± 0.02 | 0.17 ± 0.03 | 0.14 ± 0.01 | 0.15 ± 0.03 | 0.16 ± 0.01 | 0.12 ± 0.01 | 0.14 ± 0.01 | 0.15 ± 0.03 | 0.12 ± 0.01 | 0.14 ± 0.01 |
14 | Thymol | 1193 | 46.31 ± 1.43 | 51.81 ± 1.13 | 57.11 ± 1.34 | 58.23 ± 1.43 | 48.62 ± 1.08 | 55.19 ± 1.12 | 58.28 ± 1.28 | 61.06 ± 1.19 | 53.91 ± 1.21 | 57.81 ± 1.25 | 61.01 ± 1.67 | 64.61 ± 1.32 |
15 | Carvacrol | 1214 | 5.42 ± 0.16 | 5.97 ± 0.18 | 6.95 ± 0.21 | 7.87 ± 0.31 | 5.93 ± 0.11 | 7.68 ± 0.18 | 8.75 ± 0.21 | 9.46 ± 0.24 | 6.14 ± 0.17 | 7.98 ± 0.22 | 9.21 ± 0.25 | 9.83 ± 0.19 |
16 | β-Caryophyllene | 1322 | 4.21 ± 0.15 | 4.11 ± 0.10 | 4.03 ± 0.12 | 3.95 ± 0.05 | 4.08 ± 0.08 | 3.82 ± 0.14 | 3.58 ± 0.07 | 3.26 ± 0.05 | 3.69 ± 0.12 | 3.32 ± 0.09 | 2.94 ± 0.11 | 2.80 ± 0.08 |
17 | Aromadendrene | 1339 | 0.32 ± 0.01 | 0.34 ± 0.02 | 0.31 ± 0.01 | 0.32 ± 0.01 | 0.30 ± 0.02 | 0.31 ± 0.01 | 0.28 ± 0.01 | 0.37 ± 0.01 | 0.36 ± 0.02 | 0.32 ± 0.01 | 0.37 ± 0.01 | 0.36 ± 0.02 |
18 | α-Humulene | 1356 | 0.14 ± 0.01 | 0.15 ± 0.01 | 0.14 ± 0.01 | 0.10 ± 0.00 | 0.13 ± 0.02 | 0.17 ± 0.01 | 0.13 ± 0.00 | 0.14 ± 0.01 | 0.12 ± 0.00 | 0.12 ± 0.00 | 0.14 ± 0.01 | 0.11 ± 0.00 |
19 | Viridiflorene | 1391 | 0.28 ± 0.03 | 0.25 ± 0.02 | 0.25 ± 0.02 | 0.26 ± 0.02 | 0.24 ± 0.02 | 0.25 ± 0.03 | 0.22 ± 0.02 | 0.27 ± 0.02 | 0.22 ± 0.02 | 0.21 ± 0.01 | 0.27 ± 0.01 | 0.25 ± 0.02 |
20 | Acetovanillone | 1460 | 4.22 ± 0.28 | 3.61 ± 0.22 | 3.32 ± 0.21 | 3.05 ± 0.16 | 3.73 ± 0.17 | 3.67 ± 0.15 | 3.63 ± 0.18 | 3.69 ± 0.24 | 3.61 ± 0.21 | 3.55 ± 0.12 | 3.43 ± 0.16 | 3.39 ± 0.19 |
21 | Spathulenol | 1478 | 0.81 ± 0.05 | 0.84 ± 0.09 | 0.75 ± 0.08 | 0.69 ± 0.04 | 0.79 ± 0.10 | 0.76 ± 0.05 | 0.68 ± 0.09 | 0.72 ± 0.06 | 0.80 ± 0.07 | 0.75 ± 0.04 | 0.78 ± 0.03 | 0.75 ± 0.05 |
22 | Caryophyllene oxide | 1483 | 0.99 ± 0.23 | 0.94 ± 0.16 | 0.87 ± 0.11 | 0.86 ± 0.14 | 0.76 ± 0.12 | 0.85 ± 0.10 | 0.87 ± 0.19 | 0.83 ± 0.11 | 0.88 ± 0.13 | 0.87 ± 0.15 | 0.91 ± 0.21 | 0.91 ± 0.18 |
Total (%) | 94.61 | 97.56 | 97.26 | 96.89 | 93.68 | 96.69 | 97.63 | 98.18 | 94.51 | 96.28 | 97.94 | 97.96 |